How does one know which kanji pronunciation to use

I know about the On’yomi and Kun’yomi system, but I don’t know how to use them properly and even then, some characters have multiple On’yomi and Kun’yomi, which one do I use or must I memorise all of them

Like how does 二人 (ふたる) become ニ (に) & 人 (ひと)

And 行 has 呉音, 唐音 yada yada

How do I know which one to use in a given scenario? Thanks!

by MemeyMe08

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